It is not yet possible to configure BlackBerry OS 10 devices to connect to BlackBerry Enterprise Servers, you may use ActiveSync to connect. This article describes the process of connecting BlackBerry OS 10 device to your Exchange mailbox via ActiveSync.
BlackBerry Enterprise Service is not needed to connect in such cases. ActiveSync service must be enabled for your mailbox in order for the device to connect successfully. Read the Knowledge Base article How Do I Enable ActiveSync Service For A User?
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